Long-term thermal stability of fatty acid anion-based ionic liquids
نویسندگان
چکیده
Isothermal and dynamic methodologies were used to study the thermal degradation of 8 novel fatty acid anion-based ionic liquids (FAILs): methyltrioctylammonium hexanoate [N8,8,8,1][C6:0], octanoate [N8,8,8,1][C8:0], tetrahexylammonium [N6,6,6,6][C8:0], laurate [N8,8,8,1][C12:0], palmitate [N8,8,8,1][C16:0], [N6,6,6,6][C16:0], stearate [N8,8,8,1][C18:0] oleate [N8,8,8,1][C18:1]. The stability these FAILs is controlled by both cation anion most samples have an onset decomposition temperature (Tonset) below 200 °C. All exhibited lower under a nitrogen atmosphere than commercially available ILs tested previously in lubrication studies, particularly when compared those containing [NTf2]? anion. [N8,8,8,1][C6:0] [N8,8,8,1][C8:0] showed highest long-term stability, probably related their stronger anion-cation electrostatic interaction. This led multi-step mechanism observed DTG results. Finally, isoconversional modelling for [N8,8,8,1][C12:0] agrees with isothermal
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ژورنال
عنوان ژورنال: Journal of Molecular Liquids
سال: 2021
ISSN: ['0167-7322', '1873-3166']
DOI: https://doi.org/10.1016/j.molliq.2021.115492